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Wiley Series on Electrocatalysis and Electrochemistry
Fuel Cell Catalysis A Surface Science Approach
A Core reference on fuel cell catalysis
Fuel cells represent an important alternative energy source and a very active area of research. Fuel Cell Catalysis brings together world leaders in this field, providing a unique combination of state-of-the-art theory and computational and experimental methods. With an emphasis on understanding fuel cell catalysis at the molecular level, this text covers fundamental principles, future challenges, and important current research themes.
Fuel Cell Catalysis:
- Provides a molecular-level description of catalysis for low-temperature polymer-electrolyte membrane fuel cells, including both hydrogen-oxygen cells and direct alcohol cells
- Examines catalysis issues of both anode and cathode such as oxygen reduction, alcohol oxidation, and CO tolerance
- Features a timely and forward-looking approach through emphasis on novel aspects such as computation and bio-inspiration
- Reviews the use and potential of surface-sensitive techniques like vibrational spectroscopy (IR, Raman, nonlinear spectroscopy, laser), scanning tunneling microscopy, X-ray scattering, NMR, electrochemical techniques, and more
- Reviews the use and potential of such modern computational techniques as DFT, ab initio MD, kinetic Monte Carlo simulations, and more
- Surveys important trends in reactivity and structure sensitivity, nanoparticles, "dynamic" catalysis, electrocatalysis vs. gas-phase catalysis, new experimental techniques, and nontraditional catalysts
This cutting-edge collection offers a core reference for electrochemists, electrocatalysis researchers, surface and physical chemists, chemical and automotive engineers, and researchers in academia, research institutes, and industry.
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Preface to the Wiley Series on Electrocatalysis and Electrochemistry | p. vii |
Preface | p. ix |
List of Contributors | p. xi |
Electrocatalysis of Oxygen Reduction in Polymer Electrolyte Fuel Cells: A Brief History and a Critical Examination of Present Theory and Diagnostics | p. 1 |
Electrochemical Electron Transfer: From Marcus Theory to Electrocatalysis | p. 31 |
Electrocatalysis and Catalyst Screening from Density Functional Theory Calculations | p. 57 |
First-Principles Simulation of the Active Sites and Reaction Environment in Electrocatalysis | p. 93 |
Ab Initio Atomistic Thermodynamics for Fuel Cell Catalysis | p. 129 |
Mechanisms of the Oxidation of Carbon Monoxide and Small Organic Molecules at Metal Electrodes | p. 159 |
Clues for the Molecular-Level Understanding of Electrocatalysis on Single-Crystal Platinum Surfaces Modified by p-Block Adatoms | p. 209 |
Electrochemistry at Well-Characterized Bimetallic Surfaces Vojislav | p. 245 |
Recent Development in the Electrocatalysis of the O2 Reduction Reaction | p. 271 |
Electrocatalysis at Platinum and Bimetallic Alloys | p. 317 |
Electrocatalysis for the Direct Alcohol Fuel Cell | p. 343 |
Broadband Sum Frequency Generation Studies of Surface Intermediates Involved in Fuel Cell Electrocatalysis | p. 375 |
Methanol, Formaldehyde, and Formic Acid Adsorption/Oxidation on a Carbon-Supported Pt Nanoparticle Fuel Cell Catalyst: A Comparative Quantitative DEMS Study | p. 411 |
The Effect of Structurally Well-Defined Pt Modification on the Electronchemical and Electrocatalytic Properties of Ru(0001) Electrodes | p. 465 |
Size Effects in Electrocatalysis of Fuel Cell Reactions on Supported Metal Nanoparticles | p. 507 |
Support and Particle Size Effects in Electrocatalysis | p. 567 |
Electrocatalysis for Fuel Cells at Enzyme-Modified Electrodes | p. 593 |
Metalloporphyrin Catalysts of Oxygen Reduction | p. 637 |
Index | p. 695 |
Table of Contents provided by Ingram. All Rights Reserved. |
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Fuel cells represent an important alternative energy source. This seminal work brings together world leaders in the field to provide a unique combination of state-of-the-art theory and computational and experimental methods, emphasizing molecular understanding of fuel cell catalysis. It covers fundamental principles and future challenges. It discusses research themes in the surface science approach to catalytic reactions at the solid-liquid and solid-membrane interface relevant to fuel cells. This is a core reference for electrochemists, electrocatalysis researchers, surface and physical chemists, chemical and automotive engineers, and researchers in academia, research institutes, and industry.
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